a)

Gọi : \(\left\{{}\begin{matrix}n_{NaCl}=a\left(mol\right)\\n_{KI}=b\left(mol\right)\end{matrix}\right.\)

NaCl + AgNO₃ → AgCl + NaNO₃

a..............a...............a..............................(mol)

KI + AgNO₃→ AgI + KNO₃

b.......b..............b..................................(mol)

Ta có :

\(n_{AgNO_3} = a + b = 0,25.2 = 0,5(mol)\)

\(m_{kết\ tủa} = 143,5a + 235b = 103,775\)(gam)

Suy ra : a = 0,15 ; b = 0,35

Vậy :

\(C_{M_{NaCl}} = \dfrac{0,15}{0,4} = 0,375M\\ C_{M_{KI}} = \dfrac{0,35}{0,4} = 0,875M\)

b)

Sau phản ứng, dung dịch gồm : \(\left\{{}\begin{matrix}NaNO_3:0,15\left(mol\right)\\KNO_3:0,35\left(mol\right)\end{matrix}\right.\)

Suy ra : 

\(m_{NaNO_3} = 0,15.85 = 12,75(gam)\\ m_{KNO_3} = 0,35.101 = 35,35(gam)\)

a)

$AgNO_3 + HCl \to AgCl + HNO_3$
Theo PTHH : 

$n_{AgCl} = n_{HCl} = n_{AgNO_3} = \dfrac{340.10\%}{170} =0,2(mol)$

$m_{dd\ HCl} = \dfrac{0,2.36,5}{7,3\%} = 100(gam)$

b)

$m_{AgCl} = 0,2.143,5 = 28,7(gam)$

c)

$m_{dd\ sau\ pư} = 340 + 100 -28,7 = 411,3(gam)$

$n_{HNO_3} = n_{AgNO_3} = 0,2(mol)$
$\Rightarrow C\%_{HNO_3} = \dfrac{0,2.63}{411,3}.100\% = 3,06\%$

\(n_{NaCl}=\dfrac{3,51}{58,5}=0,06\left(mol\right)\)

a) Pt : \(NaCl+AgNO_3\rightarrow NaNO_3+AgCl|\)

              1               1                1             1

           0,06            0,06          0,06         0,06

a) \(n_{AgCl}=\dfrac{0,06.1}{1}=0,06\left(mol\right)\)

⇒ \(m_{AgCl}=0,06.143,5=8,61\left(g\right)\)

b) \(n_{AgNO3}=\dfrac{0,06.1}{1}=0,06\left(mol\right)\)

\(V_{ddAgNO3}=\dfrac{0,06}{0,2}=0,3\left(l\right)\)

c) \(n_{NaNO3}=\dfrac{0,06.1}{1}=0,06\left(mol\right)\)

\(C_{M_{NaNO3}}=\dfrac{0,06}{0,3}=0,2\left(M\right)\)

 Chúc bạn học tốt

\(a,n_{NaCl}=\dfrac{3,51}{58,5}=0,06(mol)\\ PTHH:NaCl+AgNO_3\to AgCl\downarrow+NaNO_3\\ \Rightarrow n_{AgCl}=0,06(mol)\\ \Rightarrow m_{AgCl}=0,06.143,5=8,61(g)\\ b,n_{AgNO_3}=0,06(mol)\\ \Rightarrow V_{dd_{AgNO_3}}=\dfrac{0,06}{0,2}=0,3(l)\\ c,n_{NaNO_3}=0,06(mol);V_{dd_{NaNO_3}}=V_{dd(\text {phản ứng})}=0,3(l)\\ \Rightarrow C_{M_{NaNO_3}}=\dfrac{0,06}{0,3}=0,2M\)

PTHH: \(NaCl+AgNO_3\rightarrow NaNO_3+AgCl\downarrow\)

Ta có: \(n_{NaCl}=0,2\cdot0,5=0,1\left(mol\right)=n_{AgNO_3}=n_{AgCl}\)

\(\Rightarrow\left\{{}\begin{matrix}C_{M_{AgNO_3}}=\dfrac{0,1}{0,4}=0,25\left(M\right)\\m_{AgCl}=0,1\cdot143,5=14,35\left(g\right)\end{matrix}\right.\)

nCaCl2 = 3,33/111 = 0,03 (mol)

PTHH: CaCl2 + 2AgNO3 -> 2AgCl + Ca(NO3)2

0,03 ---> 0,06 ---> 0,06

mAgNO3 = 0,06 . 170 = 10,2 (g)

mddAgNO3 = 10,2/15% = 68 (g)

mAgCl = 0,06 . 143,5 = 8,61 (g)

CaCl2+2AgNO3->2AgCl+Ca(NO3)2
0,03-----0,06-----------0,06 mol

n CaCl2=0,03 mol

->m AgNO3=0,06.170=10,2g

->m dd AgNO3=68g

=>m Agcl=0,06.143,5=8,61g

Đáp án B

Đặt số mol các chất là KCl: a mol ; NaCl: b mol.

Đáp án A

\(a,n_{Cl_2}=\dfrac{15,62}{71}=0,22\left(mol\right)\\ Đặt:n_{Fe}=a\left(mol\right);n_{Cu}=b\left(mol\right)\left(a,b>0\right)\\ 2Fe+3Cl_2\rightarrow\left(t^o\right)2FeCl_3\\ Cu+Cl_2\rightarrow\left(t^o\right)CuCl_2\\ \Rightarrow\left\{{}\begin{matrix}56a+64b=10,88\\1,5a+b=0,22\end{matrix}\right.\Leftrightarrow\left\{{}\begin{matrix}a=0,08\\b=0,1\end{matrix}\right.\\ \Rightarrow\%m_{Fe}=\dfrac{0,08.56}{10,88}.100\approx41,176\%\Rightarrow\%m_{Cu}\approx58,824\%\\ b,FeCl_3+3AgNO_3\rightarrow Fe\left(NO_3\right)_3+3AgCl\downarrow\\ CuCl_2+2AgNO_3\rightarrow Cu\left(NO_3\right)_2+2AgCl\\ n_{AgNO_3}=3.0,08+2.0,1=0,44\left(mol\right)\\ m_{AgNO_3}=0,24.170=40,8\left(g\right)\\ m_{ddAgNO_3}=\dfrac{40,8}{24\%}=170\left(g\right)\)

\(c,2NaI+Cl_2\rightarrow2NaCl+I_2\\ n_{NaI}=2.n_{Cl_2}=2.0,22=0,44\left(mol\right)\Rightarrow a=C_{MddNaI}=\dfrac{0,44}{0,1}=4,4\left(M\right)\\ n_{I_2}=n_{Cl_2}=0,22\left(mol\right)\Rightarrow m_{I_2}=254.0,22=55,88\left(g\right)\)

\(d,MnO_2+4HCl_{\left(đặc\right)}\rightarrow\left(t^o\right)MnCl_2+Cl_2+2H_2O\\ n_{MnO_2}=n_{Cl_2}=0,22\left(mol\right)\\ \Rightarrow x=m_{MnO_2}=87.0,22=19,14\left(g\right)\\ n_{HCl}=4.0,22=0,88\left(mol\right)\\ y=C_{MddHCl}=\dfrac{0,88}{0,05}=17,6\left(M\right)\)